Novel approach with polyfluorene/polydisulfide copolymer binder for high-capacity silicon anode in lithium-ion batteries

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dc.authoridTaşkın, Omer Suat/0000-0002-6284-1337en_US
dc.authoridBULUT, Emrah/0000-0002-7623-8088en_US
dc.authoridGüzel, Emre/0000-0002-1142-3936en_US
dc.authoridYuca, Neslihan/0000-0002-4566-296Xen_US
dc.contributor.authorBulut, Emrah
dc.contributor.authorGüzel, Emre
dc.contributor.authorYuca, Neslihan
dc.contributor.authorTaşkın, Omer S.
dc.date.accessioned2024-07-12T21:37:57Z
dc.date.available2024-07-12T21:37:57Z
dc.date.issued2020en_US
dc.department[Belirlenecek]en_US
dc.description.abstractIn this study, as a novel design with the collaboration of a fluorene and sulfide-based copolymer for Li-ion battery application is presented. Polyfluorene-co-polydisulfide is prepared with desired functional groups to yield a conductivity and good adhesion. These critical and important features are performed by preparing polymers with proper functional groups. The preparation process is accomplished via Suzuki coupling process under Pd catalyst by combining separately synthesized 4,4 '-dibromodiphenyl disulfide in combination with 9,9-dioctylfluorene-2,7-bis(trimethylborate). The fully obtained capacity of the silicon particles, that is, at C/10 with the capacity of 1250 mAh g(-1) after the 500th cycle, approves the good performance by preserving capacity stability till 600th cycles. The designed and synthesized polymer binder with different functionalities and carbon nanotube additive show better characteristics such as conductivity, high polarity, and binding adhesion. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48303.en_US
dc.identifier.doi10.1002/app.48303
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85070058718en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/app.48303
dc.identifier.urihttps://hdl.handle.net/20.500.12415/6980
dc.identifier.volume137en_US
dc.identifier.wosWOS:000479845300001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmzKY04322
dc.subjectDisulfide-Based Polymer Binderen_US
dc.subjectLithium-Ion Batteriesen_US
dc.subjectSilicon Anodeen_US
dc.subjectSuzuki Couplingen_US
dc.titleNovel approach with polyfluorene/polydisulfide copolymer binder for high-capacity silicon anode in lithium-ion batteriesen_US
dc.typeArticle
dspace.entity.typePublication

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